HuagongsheHuagongshe Chemistry Print Report · For research reference only
methyl 3-[N'-benzyloxycarbonyl-hydrazinocarbonyl)-benzoate → Methyl 3-(hydrazinecarbonyl)benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | methyl 3-[N'-benzyloxycarbonyl-hydrazinocarbonyl)-benzoate | HCID 12571328 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl 3-(hydrazinecarbonyl)benzoate | HCID 12571330 | — |
Reaction Steps
14.6 g (44.5 mmol) methyl 3-[N′-benzyloxycarbonyl-hydrazinocarbonyl)-benzoate are dissolved in 75 mL methanol and hydrogenated in the presence of palladium on charcoal (10%) at ambient temperature and 3 bar hydrogen pressure. The catalyst is filtered off and the filtrate is freed from solvent. White solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07405232B2 |
| Source dataset | uspto-grants-2008_07 |
| ORD ID | ord-a1e0f2910aa3425b88f484fa6c6a9664 |
| Source note | uspto-grants-2008_07 |