1,2-Dimethoxyethane → 2-(2',4'-Dichloro-4-cyclopropylbiphenyl-3-yl)-cyclopentane-1,3-dione

HRID 799437Notes

Reaction equation

HRID 799437 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:15]2[CH2:16][CH2:17]2)[c:6]([CH:8]2[C:9](=[O:14])[CH2:10][CH2:11][C:12]2=[O:13])[cH:7]1.[CH3:31][O:32][CH2:33][CH2:34][O:35][CH3:36].[Cl:18][c:19]1[c:20]([B:26]([OH:27])[OH:28])[cH:21][cH:22][c:23]([Cl:25])[cH:24]1.[Cs+:30].[F-:29]>>[c:2]1(-[c:20]2[c:19]([Cl:18])[cH:24][c:23]([Cl:25])[cH:22][cH:21]2)[cH:3][cH:4][c:5]([CH:15]2[CH2:16][CH2:17]2)[c:6]([CH:8]2[C:9](=[O:14])[CH2:10][CH2:11][C:12]2=[O:13])[cH:7]1

Participants

6

Reactant 5

HCID 80711,2-DimethoxyethaneHCID 28179Fluoride IonHCID 104967Cesium cationHCID 2734659(2,4-Dichlorophenyl)boronic acidHCID 666768602-(5-Bromo-2-cyclopropylphenyl)cyclopentane-1,3-dione

Product 1

HCID 669914682-(2',4'-Dichloro-4-cyclopropylbiphenyl-3-yl)-cyclopentane-1,3-dione

Sources & evidence

ORD record
ord-2bc63c00c5a84a5e9e890938f1515ed8
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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