Dimethyl Sulfoxide → 1-(4-Chlorophenyl)-1-t-butyl-ethylene oxide

HRID 799846Notes

Reaction equation

HRID 799846 reaction equation
[C:9]([CH3:10])([CH3:11])([CH3:12])[C:13](=[O:14])[c:15]1[cH:16][cH:17][c:18]([Cl:21])[cH:19][cH:20]1.[CH3:22][S:23](=[O:24])[CH3:25].[CH3:4][S+:5]([CH3:6])([CH3:7])=[O:8].[H-:1].[I-:3].[Na+:2]>>[CH2:4]1[C:13]([C:9]([CH3:10])([CH3:11])[CH3:12])([c:15]2[cH:16][cH:17][c:18]([Cl:21])[cH:19][cH:20]2)[O:14]1

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 30165Iodide IonHCID 74499TrimethylsulfoxoniumHCID 166653HydrideHCID 111380501-(4-Chlorophenyl)-2,2-dimethylpropan-1-one

Product 1

HCID 139839361-(4-Chlorophenyl)-1-t-butyl-ethylene oxide

Sources & evidence

ORD record
ord-bc9893cfbdb54c6aa0e14ae1b40f7ccf
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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