Bromide ion → 1,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[4-(4-fluoro-phenyl)-pent-4-enyloxy]-benzene

HRID 801511Notes

Reaction equation

HRID 801511 reaction equation
[Br-:35].[CH3:28][c:29]1[cH:30][cH:31][cH:32][cH:33][cH:34]1.[CH3:36][P+:37]([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)([c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1)[c:50]1[cH:51][cH:52][cH:53][cH:54][cH:55]1.[Cl:1][c:2]1[c:3]([O:4][CH2:5][CH2:6][CH2:7][C:8](=[O:9])[c:10]2[cH:11][cH:12][c:13]([F:16])[cH:14][cH:15]2)[c:17]([Cl:27])[cH:18][c:19]([O:21][CH2:22][CH:23]=[C:24]([Cl:25])[Cl:26])[cH:20]1>>[Cl:1][c:2]1[c:3]([O:4][CH2:5][CH2:6][CH2:7][C:8]([c:10]2[cH:11][cH:12][c:13]([F:16])[cH:14][cH:15]2)=[CH2:28])[c:17]([Cl:27])[cH:18][c:19]([O:21][CH2:22][CH:23]=[C:24]([Cl:25])[Cl:26])[cH:20]1

Participants

5

Reactant 4

HCID 259Bromide ionHCID 1140TolueneHCID 74506TriphenylmethylphosphoniumHCID 866130884-[2,6-Dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-1-(4-fluoro-phenyl)-butan-1-one

Product 1

HCID 579857921,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[4-(4-fluoro-phenyl)-pent-4-enyloxy]-benzene

Sources & evidence

ORD record
ord-972f4155476d4452b651cf85a49befcf
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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