Acetate → 1-(3-Methoxypropyl)-3,3,6-trimethyl-1,3-dihydroindol-2-one

HRID 802027Notes

Reaction equation

HRID 802027 reaction equation
[Br:7][c:8]1[c:9]([N:15]([C:16]([CH:17]([CH3:18])[CH3:19])=[O:20])[CH2:21][CH2:22][CH2:23][O:24][CH3:25])[cH:10][c:11]([CH3:14])[cH:12][cH:13]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[Na+:6].[O-:33][C:34]([CH3:35])=[O:36].[O-:37][C:38]([CH3:39])=[O:40].[O:26]1[CH2:27][CH2:28][O:29][CH2:30][CH2:31]1.[Pd+2:32]>>[c:8]12[c:9]([cH:10][c:11]([CH3:14])[cH:12][cH:13]1)[N:15]([CH2:21][CH2:22][CH2:23][O:24][CH3:25])[C:16](=[O:20])[C:17]2([CH3:18])[CH3:19]

Participants

7

Reactant 6

HCID 175Acetate2×HCID 923Sodium ionHCID 312751,4-DioxaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 45749132-Methylpropan-2-olateHCID 68505459N-(2-bromo-5-methylphenyl)-N-(3-methoxypropyl)isobutyramide

Product 1

HCID 685021401-(3-Methoxypropyl)-3,3,6-trimethyl-1,3-dihydroindol-2-one

Sources & evidence

ORD record
ord-c5810df8d9b7482bb408621bd73b2120
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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