Acetone → Methyl 3-chloro-5-(3,3-dichloroallyloxy)-2-hydroxybenzoate

HRID 802050Notes

Reaction equation

HRID 802050 reaction equation
[Br-:33].[Br-:34].[C:20](=[O:21])([O-:22])[O-:23].[CH2:28]([O:29][CH2:30][CH3:31])[CH3:32].[CH3:36][C:37](=[O:38])[CH3:39].[CH3:40][c:41]1[cH:42][cH:43][cH:44][cH:45][cH:46]1.[CH3:47][CH2:48][O:49][CH2:50][CH3:51].[Cl:14][C:15](=[CH:16][CH2:17][Cl:18])[Cl:19].[Cl:1][c:2]1[c:3]([OH:13])[c:4]([C:5](=[O:6])[O:7][CH3:8])[cH:9][c:10]([OH:12])[cH:11]1.[I-:27].[K+:24].[K+:25].[Mg+2:35].[Na+:26].[OH2:52]>>[Cl:1][c:2]1[c:3]([OH:13])[c:4]([C:5](=[O:6])[O:7][CH3:8])[cH:9][c:10]([O:12][CH2:17][CH:16]=[C:15]([Cl:14])[Cl:19])[cH:11]1

Participants

13

Reactant 12

HCID 180AcetoneHCID 259Bromide ion2×HCID 813Potassium Cation2×HCID 888Magnesium CationHCID 923Sodium ionHCID 962WaterHCID 1140TolueneHCID 3283Diethyl Ether2×HCID 173781,1,3-TrichloropropeneHCID 19660Carbonate IonHCID 30165Iodide IonHCID 22318625Methyl 3-chloro-2,5-dihydroxybenzoate

Product 1

HCID 22318615Methyl 3-chloro-5-(3,3-dichloroallyloxy)-2-hydroxybenzoate

Sources & evidence

ORD record
ord-ee7db0ca9fa84e24a77245f61bda5569
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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