Bicarbonate Ion → 3-(4-Triisopropylsilanyloxymethyl-benzoyl)-benzonitrile

HRID 802193Notes

Reaction equation

HRID 802193 reaction equation
[C:32](=[O:33])([O-:34])[OH:35].[Cl:29][CH2:30][Cl:31].[Na+:36].[OH:1][CH:2]([c:3]1[cH:4][c:5]([C:6]#[N:7])[cH:8][cH:9][cH:10]1)[c:11]1[cH:12][cH:13][c:14]([CH2:17][O:18][Si:19]([CH:20]([CH3:21])[CH3:22])([CH:23]([CH3:24])[CH3:25])[CH:26]([CH3:27])[CH3:28])[cH:15][cH:16]1>>[O:1]=[C:2]([c:3]1[cH:4][c:5]([C:6]#[N:7])[cH:8][cH:9][cH:10]1)[c:11]1[cH:12][cH:13][c:14]([CH2:17][O:18][Si:19]([CH:20]([CH3:21])[CH3:22])([CH:23]([CH3:24])[CH3:25])[CH:26]([CH3:27])[CH3:28])[cH:15][cH:16]1

Participants

5

Reactant 4

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 6344DichloromethaneHCID 666996123-[Hydroxy-(4-triisopropylsilanyloxymethyl-phenyl)-methyl]-benzonitrile

Product 1

HCID 574383603-(4-Triisopropylsilanyloxymethyl-benzoyl)-benzonitrile

Sources & evidence

ORD record
ord-53e603a2d34342d0a12a0545a7cf027e
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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