Acetonitrile → Benzene, 1-chloro-4-[[(4-nitrophenyl)methyl]thio]-

HRID 802541Notes

Reaction equation

HRID 802541 reaction equation
[CH3:24][C:25]#[N:26].[CH3:27][N:28]([CH3:29])[P:30](=[O:31])([N:32]([CH3:33])[CH3:34])[N:35]([CH3:36])[CH3:37].[Cl:12][c:13]1[cH:14][cH:15][c:16]([S:19][Si:20]([CH3:21])([CH3:22])[CH3:23])[cH:17][cH:18]1.[O-:1][N+:2](=[O:3])[c:4]1[cH:5][cH:6][c:7]([CH2:8][Br:9])[cH:10][cH:11]1>>[O-:1][N+:2](=[O:3])[c:4]1[cH:5][cH:6][c:7]([CH2:8][S:19][c:16]2[cH:15][cH:14][c:13]([Cl:12])[cH:18][cH:17]2)[cH:10][cH:11]1

Participants

5

Reactant 4

HCID 6342AcetonitrileHCID 12679HexamethylphosphoramideHCID 660114-Nitrobenzyl bromideHCID 111068011-Chloro-4-[(trimethylsilyl)thio]benzene

Product 1

HCID 2817792Benzene, 1-chloro-4-[[(4-nitrophenyl)methyl]thio]-

Sources & evidence

ORD record
ord-59a5d87a3f6e4a24af96068634e0ca94
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…