Dichloromethane → 5-Chloro-1,3-dihydroisobenzofuran-1-ol

HRID 803144Notes

Reaction equation

HRID 803144 reaction equation
[CH2:13]([Al+:14][CH2:15][CH:16]([CH3:17])[CH3:18])[CH:19]([CH3:20])[CH3:21].[Cl:1][c:2]1[cH:3][c:4]2[c:9]([cH:10][cH:11]1)[C:7](=[O:8])[O:6][CH2:5]2.[Cl:22][CH2:23][Cl:24].[H-:12]>>[Cl:1][c:2]1[cH:3][c:4]2[c:9]([cH:10][cH:11]1)[CH:7]([OH:8])[O:6][CH2:5]2

Participants

5

Reactant 4

HCID 6344DichloromethaneHCID 166653HydrideHCID 2417375-Chloro-1,3-dihydro-2-benzofuran-1-oneHCID 16686348Bis(2-methylpropyl)alumanylium

Product 1

HCID 693101565-Chloro-1,3-dihydroisobenzofuran-1-ol

Sources & evidence

ORD record
ord-d3d90f564f7240bd93be8d5ac5f71bda
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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