2-(Trifluoromethylthio)ethyl Trifluoromethanesulfonate → HCID 86673271, compound

HRID 80406Notes

Reaction equation

HRID 80406 reaction equation
[Cl:1][C:2]1[N:7]=[CH:6][C:5]([CH2:8][S:9]([CH2:12][C:13]#[N:14])(=[O:11])=[O:10])=[CH:4][CH:3]=1.[F:15][C:16]([S:19][CH2:20][CH2:21]OS(C(F)(F)F)(=O)=O)([F:18])[F:17]>>[Cl:1][C:2]1[N:7]=[CH:6][C:5]([CH2:8][S:9]([CH:12]([CH2:21][CH2:20][S:19][C:16]([F:18])([F:17])[F:15])[C:13]#[N:14])(=[O:10])=[O:11])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 252420282-(Trifluoromethylthio)ethyl TrifluoromethanesulfonateHCID 86673272(6-Chloro-pyridin-3-ylmethanesulfonyl)-acetonitrile

Product 1

HCID 86673271HCID 86673271, compound

Procedure

Compound II-7 was prepared from (6-chloro-pyridin-3-ylmethanesulfonyl)-acetonitrile and trifluoro-methanesulfonic acid 2-trifluoromethylsulfanyl-ethyl ester as described for compound II-1.

Sources & evidence

ORD record
ord-6884ce4bb24f49ba80e2f8a5200667b5
Source dataset
uspto-grants-2014_09
Patent number
US08846569B2

Reaction notes

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