2-(Trifluoromethylthio)ethyl Trifluoromethanesulfonate → HCID 53236482, compound

HRID 80408Notes

Reaction equation

HRID 80408 reaction equation
[F:1][C:2]([F:17])([F:16])[C:3]1[CH:8]=[CH:7][C:6]([CH2:9][S:10]([CH2:13][C:14]#[N:15])(=[O:12])=[O:11])=[CH:5][CH:4]=1.[F:18][C:19]([S:22][CH2:23][CH2:24]OS(C(F)(F)F)(=O)=O)([F:21])[F:20]>>[F:17][C:2]([F:1])([F:16])[C:3]1[CH:4]=[CH:5][C:6]([CH2:9][S:10]([CH:13]([CH2:24][CH2:23][S:22][C:19]([F:21])([F:20])[F:18])[C:14]#[N:15])(=[O:12])=[O:11])=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 252420282-(Trifluoromethylthio)ethyl TrifluoromethanesulfonateHCID 67227712HCID 67227712, compound

Product 1

HCID 53236482HCID 53236482, compound

Procedure

Compound II-11 was prepared from (4-trifluoromethyl-phenylmethanesulfonyl)-acetonitrile and trifluoro-methanesulfonic acid 2-trifluoromethylsulfanyl-ethyl ester as described for compound II-1.

Sources & evidence

ORD record
ord-12b75d196a1041e388dba2723352236f
Source dataset
uspto-grants-2014_09
Patent number
US08846569B2

Reaction notes

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