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HRID8069

反应详情

EQUATION

反应方程式

HRID 8069 的结构方程式

REACTANTS

反应物

3
结构：c1ccncc1
HCID1049

Pyridine

C5H5N

结构：Cc1cccc(NN)c1.Cl
HCID71562

m-Tolylhydrazinium(1+) chloride

C7H11ClN2

结构：CCOC(=O)C(C(C)=O)C(C)=O
HCID79063

Ethyl 2-acetylacetoacetate

C8H12O4

PRODUCTS

生成物

1
结构：CCOC(=O)c1c(C)nn(-c2cccc(C)c2)c1C
HCID9878335

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Similar to Example 1, equimolar amounts of m-tolylhydrazine hydrochloride and 2-acetyl-3-oxo-butyric acid ethyl ester were combined in a solution of a 50% pyridine in ethanol. The resulting oil was purified by flash chromatography to yield the named product as a solid (m.p. 46.5° C.–47.5° C.).

WORKUP

后处理

  1. customThe resulting oil was purified by flash chromatography