Potassium Cation → 1-(4-But-3-ynyl-benzyl)-pyrrolidine

HRID 810479Notes

Reaction equation

HRID 810479 reaction equation
[CH3:35][OH:36].[CH3:37][CH2:38][O:39][CH2:40][CH3:41].[K+:29].[K+:30].[N+:1](=[C:3]([P:2](=[O:4])([O:5][CH3:6])[O:7][CH3:8])[C:9](=[O:10])[CH3:11])=[N-:12].[N:13]1([CH2:18][c:19]2[cH:20][cH:21][c:22]([CH2:25][CH2:26][CH:27]=[O:28])[cH:23][cH:24]2)[CH2:14][CH2:15][CH2:16][CH2:17]1.[O-:31][C:32]([O-:33])=[O:34]>>[CH:3]#[C:27][CH2:26][CH2:25][c:22]1[cH:21][cH:20][c:19]([CH2:18][N:13]2[CH2:14][CH2:15][CH2:16][CH2:17]2)[cH:24][cH:23]1

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 887MethanolHCID 3283Diethyl EtherHCID 19660Carbonate IonHCID 859698393-(4-Pyrrolidin-1-ylmethyl-phenyl)-propionaldehydeHCID 136023029(1E)-1-diazo-1-dimethoxyphosphorylpropan-2-one

Product 1

HCID 859698431-(4-But-3-ynyl-benzyl)-pyrrolidine

Sources & evidence

ORD record
ord-a6a81c0113e449fc9c3c037ddf5c4a9c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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