Acetate → 4-(1H-inden-2-yl)-2,3-dihydro-1H-cyclopenta[b]indole
Reaction equation
[Br:27][C:28]1=[CH:32][c:31]2[c:30]([cH:36][cH:35][cH:34][cH:33]2)[CH2:29]1.[CH2:15]1[CH2:16][CH2:17][c:18]2[nH:19][c:20]3[cH:21][cH:22][cH:23][cH:24][c:25]3[c:26]21.[CH2:1]1[C:2]([n:10]2[cH:11][cH:12][cH:13][cH:14]2)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21.[CH3:54][O:55][CH2:56][CH2:57][O:58][CH3:59].[CH3:60][c:61]1[cH:62][cH:63][cH:64][cH:65][cH:66]1.[K+:42].[K+:43].[K+:44].[O-:46][C:47]([CH3:48])=[O:49].[O-:50][C:51]([CH3:52])=[O:53].[P:37]([O-:38])([O-:39])([O-:40])=[O:41].[Pd+2:45]>>[CH2:1]1[C:2]([n:19]2[c:18]3[c:26]([c:25]4[c:20]2[cH:21][cH:22][cH:23][cH:24]4)[CH2:15][CH2:16][CH2:17]3)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21Participants
10
Reactant 9
HCID 175Acetate2×
HCID 813Potassium Cation3×
HCID 1061Phosphate
HCID 1140Toluene
HCID 80711,2-Dimethoxyethane
HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)
HCID 2703051,2,3,4-Tetrahydro-cyclopenta(b)indole
HCID 5755861H-Indene, 2-bromo-
HCID 180083501-(1H-inden-2-yl)-1H-pyrroleProduct 1
Sources & evidence
- ORD record
- ord-fc1d8e17731c449bb82ebff90b2d7257
- Source dataset
- Test data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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