Potassium Cation → Cyclopropyl-(3-ethynyl-4-methylbenzyl)-methyl-amine

HRID 811639Notes

Reaction equation

HRID 811639 reaction equation
[C:20](=[O:21])([O-:22])[O-:23].[CH3:26][OH:27].[CH:1]1([N:4]([CH2:5][c:6]2[cH:7][c:8]([C:13]#[C:14][Si:15]([CH3:16])([CH3:17])[CH3:18])[c:9]([CH3:12])[cH:10][cH:11]2)[CH3:19])[CH2:2][CH2:3]1.[K+:24].[K+:25]>>[CH:1]1([N:4]([CH2:5][c:6]2[cH:7][c:8]([C:13]#[CH:14])[c:9]([CH3:12])[cH:10][cH:11]2)[CH3:19])[CH2:2][CH2:3]1

Participants

5

Reactant 4

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 57424248Cyclopropyl-methyl-(4-methyl-3-trimethylsilanylethynyl-benzyl)-amine

Product 1

HCID 21107259Cyclopropyl-(3-ethynyl-4-methylbenzyl)-methyl-amine

Sources & evidence

ORD record
ord-0be4e5d117d3457d8b788729e5309fda
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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