Dimethyl Sulfoxide → 4-(5,7-Dioxaspiro[2.5]oct-6-ylmethoxy)-2,3-dimethylpyridine 1-oxide

HRID 813559Notes

Reaction equation

HRID 813559 reaction equation
[CH2:1]1[CH2:2][C:3]12[CH2:4][O:5][CH:6]([CH2:9][OH:10])[O:7][CH2:8]2.[CH3:23][S:24]([CH3:25])=[O:26].[Cl:13][c:14]1[c:15]([CH3:22])[c:16]([CH3:21])[n+:17]([O-:20])[cH:18][cH:19]1.[H-:11].[Na+:12]>>[CH2:1]1[CH2:2][C:3]12[CH2:4][O:5][CH:6]([CH2:9][O:10][c:14]1[c:15]([CH3:22])[c:16]([CH3:21])[n+:17]([O-:20])[cH:18][cH:19]1)[O:7][CH2:8]2

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 166653HydrideHCID 98774464-Chloro-2,3-dimethyl-1-oxidopyridin-1-iumHCID 597925305,7-Dioxaspiro[2.5]oct-6-ylmethanol

Product 1

HCID 597925884-(5,7-Dioxaspiro[2.5]oct-6-ylmethoxy)-2,3-dimethylpyridine 1-oxide

Sources & evidence

ORD record
ord-f23d006da27c4c119c704f0f1b136cf5
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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