Bicarbonate Ion → 2-Chloromethyl-5,6,7-trimethoxynaphthalene

HRID 817674Notes

Reaction equation

HRID 817674 reaction equation
[CH:29]([Cl:30])([Cl:31])[Cl:32].[Na+:24].[OH2:23].[OH:1][CH2:2][c:3]1[cH:4][c:5]2[cH:6][c:7]([O:17][CH3:18])[c:8]([O:15][CH3:16])[c:9]([O:13][CH3:14])[c:10]2[cH:11][cH:12]1.[OH:25][C:26](=[O:27])[O-:28].[S:19]([Cl:20])([Cl:21])=[O:22]>>[CH2:2]([c:3]1[cH:4][c:5]2[cH:6][c:7]([O:17][CH3:18])[c:8]([O:15][CH3:16])[c:9]([O:13][CH3:14])[c:10]2[cH:11][cH:12]1)[Cl:21]

Participants

7

Reactant 6

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 962WaterHCID 6212ChloroformHCID 24386Thionyl ChlorideHCID 218915782-Hydroxymethyl-5,6,7-trimethoxynaphthalene

Product 1

HCID 218916422-Chloromethyl-5,6,7-trimethoxynaphthalene

Sources & evidence

ORD record
ord-d545ad40b2644c5bbb56664c53bbe39b
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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