Acetate → Benzyl 3-(1-ethoxycarbonylcyclopropyl)pyrrolidine-1-carboxylate

HRID 821495Notes

Reaction equation

HRID 821495 reaction equation
[C:31]([O-:32])(=[O:33])[CH3:34].[C:36]([O-:37])(=[O:38])[CH3:39].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[N:11]1[CH2:12][CH:13]([C:16]([C:17](=[O:18])[O:19][CH2:20][CH3:21])=[CH2:22])[CH2:14][CH2:15]1.[CH3:26][CH2:27][O:28][CH2:29][CH3:30].[N+:23](=[N-:24])=[CH2:25].[Pd+2:35]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[N:11]1[CH2:12][CH:13]([C:16]2([C:17](=[O:18])[O:19][CH2:20][CH3:21])[CH2:22][CH2:25]2)[CH2:14][CH2:15]1

Participants

6

Reactant 5

HCID 175Acetate2×HCID 3283Diethyl EtherHCID 9550DiazomethaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 22100507HCID 22100507, compound

Product 1

HCID 22100578Benzyl 3-(1-ethoxycarbonylcyclopropyl)pyrrolidine-1-carboxylate

Sources & evidence

ORD record
ord-2c3519dd6dd44cbda8340c94ed4534e9
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…