Fluoride Ion → N'-[5-(1-cyclopentyl-3-hydroxyprop-1-en-2-yl)thiophen-2-yl]sulfonyl-N,N-dimethylmethanimidamide

HRID 824382Notes

Reaction equation

HRID 824382 reaction equation
[CH3:19][N:20]([CH3:21])[CH:22]=[N:23][S:24](=[O:25])(=[O:26])[c:27]1[s:28][c:29]([Br:32])[cH:30][cH:31]1.[CH:1]1([CH:6]=[C:7]([CH2:8][OH:9])[B:10]2[O:11][C:12]([CH3:13])([CH3:14])[C:15]([CH3:16])([CH3:17])[O:18]2)[CH2:2][CH2:3][CH2:4][CH2:5]1.[Cs+:34].[F-:33]>>[CH:1]1([CH:6]=[C:7]([CH2:8][OH:9])[c:29]2[s:28][c:27]([S:24]([N:23]=[CH:22][N:20]([CH3:19])[CH3:21])(=[O:25])=[O:26])[cH:31][cH:30]2)[CH2:2][CH2:3][CH2:4][CH2:5]1

Participants

5

Reactant 4

HCID 28179Fluoride IonHCID 104967Cesium cationHCID 54319951N,N-Dimethyl-N'-(5-bromothiophene-2-sulfonyl)formamidineHCID 670847173-Cyclopentyl-2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-prop-2-en-1-ol

Product 1

HCID 69059184N'-[5-(1-cyclopentyl-3-hydroxyprop-1-en-2-yl)thiophen-2-yl]sulfonyl-N,N-dimethylmethanimidamide

Sources & evidence

ORD record
ord-5215b86c096c4bef98c350786b6e6a4a
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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