Acetate → Methyl (1,1-dimethyl-2-oxopropoxy)acetate

HRID 826285Notes

Reaction equation

HRID 826285 reaction equation
[C:19]([O-:20])(=[O:21])[CH3:22].[C:24]([O-:25])(=[O:26])[CH3:27].[CH3:17][OH:18].[CH3:1][C:2]([C:3]#[CH:4])([CH3:5])[O:6][CH2:7][C:8](=[O:9])[O:10][CH3:11].[Hg+2:23].[S:12]([OH:13])(=[O:14])(=[O:15])[OH:16]>>[CH3:1][C:2]([C:3]([CH3:4])=[O:13])([CH3:5])[O:6][CH2:7][C:8](=[O:9])[O:10][CH3:11]

Participants

6

Reactant 5

HCID 175Acetate2×HCID 887MethanolHCID 1118Sulfuric AcidHCID 26623Mercuric cationHCID 13005744(1,1-Dimethylprop-2-ynyloxy)acetic acid methyl ester

Product 1

HCID 85791200Methyl (1,1-dimethyl-2-oxopropoxy)acetate

Sources & evidence

ORD record
ord-53e30c54e82549f2882453c7fdb00c36
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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