Carbon Tetrachloride → Ethyl 3-Bromomethyl-5-chlorobenzo[b]thiophene-2-carboxylate

HRID 826489Notes

Reaction equation

HRID 826489 reaction equation
[Br:17][N:18]1[C:19](=[O:20])[CH2:21][CH2:22][C:23]1=[O:24].[C:25]([O:26][O:27][C:28](=[O:29])[c:30]1[cH:31][cH:32][cH:33][cH:34][cH:35]1)(=[O:36])[c:37]1[cH:38][cH:39][cH:40][cH:41][cH:42]1.[C:43]([Cl:44])([Cl:45])([Cl:46])[Cl:47].[Cl:1][c:2]1[cH:3][c:4]2[c:5]([s:6][c:7]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[c:8]2[CH3:9])[cH:15][cH:16]1>>[Cl:1][c:2]1[cH:3][c:4]2[c:5]([s:6][c:7]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[c:8]2[CH2:9][Br:17])[cH:15][cH:16]1

Participants

5

Reactant 4

HCID 5943Carbon TetrachlorideHCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 14836260Ethyl 5-chloro-3-methyl-1-benzothiophene-2-carboxylate

Product 1

HCID 14836261Ethyl 3-Bromomethyl-5-chlorobenzo[b]thiophene-2-carboxylate

Sources & evidence

ORD record
ord-b3102fde8ffb47948a0f729cf00a830c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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