Potassium Cation → Methyl 5-chloro-2-ethynylbenzoate

HRID 829125Notes

Reaction equation

HRID 829125 reaction equation
[CH3:24][OH:25].[Cl:1][c:2]1[cH:3][cH:4][c:5]([C:12]#[C:13][Si:14]([CH3:15])([CH3:16])[CH3:17])[c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11]1.[K+:18].[K+:19].[O-:20][C:21]([O-:22])=[O:23]>>[Cl:1][c:2]1[cH:3][cH:4][c:5]([C:12]#[CH:13])[c:6]([C:7](=[O:8])[O:9][CH3:10])[cH:11]1

Participants

5

Reactant 4

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 70872518Methyl 5-chloro-2-[2-(trimethylsilyl)ethynyl]benzoate

Product 1

HCID 86672667Methyl 5-chloro-2-ethynylbenzoate

Sources & evidence

ORD record
ord-35d1d13737e44b94b5550a4f96bbfc9f
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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