Acetate → HCID 57541263, compound

HRID 830624Notes

Reaction equation

HRID 830624 reaction equation
[B-:41]([F:42])([F:43])([F:44])[F:45].[Br:23][c:24]1[cH:25][cH:26][c:27]2[c:28]([c:29](=[O:39])[c:30]3[c:31]([n:32][cH:33][c:34]([Cl:36])[cH:35]3)[cH:37][cH:38]2)[cH:40]1.[C:46]([PH+:47]([C:48]([CH3:49])([CH3:50])[CH3:51])[C:52]([CH3:53])([CH3:54])[CH3:55])([CH3:56])([CH3:57])[CH3:58].[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:7][N:8]([S:9](=[O:10])(=[O:11])[CH2:12][C:13](=[O:14])[O:15][CH3:16])[c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1.[Na+:6].[O-:60][C:61]([CH3:62])=[O:63].[O-:64][C:65]([CH3:66])=[O:67].[O:68]1[CH2:69][CH2:70][O:71][CH2:72][CH2:73]1.[Pd+2:59]>>[CH3:7][N:8]([S:9](=[O:10])(=[O:11])[CH:12]([C:13](=[O:14])[O:15][CH3:16])[c:24]1[cH:25][cH:26][c:27]2[c:28]([c:29](=[O:39])[c:30]3[c:31]([n:32][cH:33][c:34]([Cl:36])[cH:35]3)[cH:37][cH:38]2)[cH:40]1)[c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 923Sodium ionHCID 26255TetrafluoroborateHCID 312751,4-DioxaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 4060964Tri-t-butylphosphoniumHCID 45749132-Methylpropan-2-olateHCID 14002850HCID 14002850, compoundHCID 159808187-Bromo-3-chloro-5H-benzo[4,5]cyclohepta[1,2-B]pyridin-5-one

Product 1

HCID 57541263HCID 57541263, compound

Sources & evidence

ORD record
ord-d68dffb5325e456997acb3c70a16fd52
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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