Acetonitrile → Ethyl 2-fluoro-3-(furan-2-yl)-3-oxopropanoate

HRID 833027Notes

Reaction equation

HRID 833027 reaction equation
[B-:14]([F:15])([F:16])([F:17])[F:18].[B-:19]([F:20])([F:21])([F:22])[F:23].[CH3:35][C:36]#[N:37].[Cl:24][CH2:25][N+:26]12[CH2:27][CH2:28][N+:29]([F:30])([CH2:31][CH2:32]1)[CH2:33][CH2:34]2.[O:1]=[C:2]([CH2:3][C:4](=[O:5])[O:6][CH2:7][CH3:8])[c:9]1[o:10][cH:11][cH:12][cH:13]1>>[O:1]=[C:2]([CH:3]([C:4](=[O:5])[O:6][CH2:7][CH3:8])[F:15])[c:9]1[o:10][cH:11][cH:12][cH:13]1

Participants

5

Reactant 4

HCID 6342AcetonitrileHCID 26255Tetrafluoroborate2×HCID 27249341-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo(2.2.2)octaneHCID 2759240Ethyl 3-(fur-2-yl)-3-oxopropanoate

Product 1

HCID 45080919Ethyl 2-fluoro-3-(furan-2-yl)-3-oxopropanoate

Sources & evidence

ORD record
ord-f89801243c8146639d82be268cfac23c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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