HRID833296

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID241

Benzene

C6H6

HCID185497

Rhodium, ion(Rh2 )

Rh+2

结构：COC(=O)C(=[N+]=[N-])c1cc(C(F)(F)F)cc(C(F)(F)F)c1

HCID54200568

未命名化合物

结构：N#CC1CC2(c3ccccc3)C(O)CCC1N2Cc1ccccc1

HCID69684778

未命名化合物

PRODUCTS

生成物

结构：COC(=O)C(OC1CCC2C(C#N)CC1(c1ccccc1)N2Cc1ccccc1)c1cc(C(F)(F)F)cc(C(F)(F)F)c1

HCID88039289

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2837cf4ab6f045019265fedc29597c20
来源数据集: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Test data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[C:52]([O-:53])(=[O:54])[CH3:55].[C:57]([O-:58])(=[O:59])[CH3:60].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[N:8]1[C:9]2([c:19]3[cH:20][cH:21][cH:22][cH:23][cH:24]3)[CH:10]([OH:18])[CH2:11][CH2:12][CH:13]1[CH:14]([C:16]#[N:17])[CH2:15]2.[N+:25](=[N-:26])=[C:27]([C:28](=[O:29])[O:30][CH3:31])[c:32]1[cH:33][c:34]([C:42]([F:43])([F:44])[F:45])[cH:35][c:36]([C:38]([F:39])([F:40])[F:41])[cH:37]1.[Rh+2:56].[cH:46]1[cH:47][cH:48][cH:49][cH:50][cH:51]1>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[N:8]1[C:9]2([c:19]3[cH:20][cH:21][cH:22][cH:23][cH:24]3)[CH:10]([O:18][CH:27]([C:28](=[O:29])[O:30][CH3:31])[c:32]3[cH:33][c:34]([C:42]([F:43])([F:44])[F:45])[cH:35][c:36]([C:38]([F:39])([F:40])[F:41])[cH:37]3)[CH2:11][CH2:12][CH:13]1[CH:14]([C:16]#[N:17])[CH2:15]2