Carbon Tetrachloride → 1,4-Dimethyl-3-(2'-nitrophenyl)pyrrole-carbaldehyde

HRID 836326Notes

Reaction equation

HRID 836326 reaction equation
[C:4]([Cl:5])([Cl:6])([Cl:7])[Cl:8].[CH2:1]([Cl:2])[Cl:3].[CH3:9][n:10]1[c:11]([CH2:25][OH:26])[c:12](-[c:16]2[c:17]([N+:22](=[O:23])[O-:24])[cH:18][cH:19][cH:20][cH:21]2)[c:13]([CH3:15])[cH:14]1.[O:27]=[Mn:28]=[O:29]>>[CH3:9][n:10]1[c:11]([CH:25]=[O:26])[c:12](-[c:16]2[c:17]([N+:22](=[O:23])[O-:24])[cH:18][cH:19][cH:20][cH:21]2)[c:13]([CH3:15])[cH:14]1

Participants

5

Reactant 4

HCID 5943Carbon TetrachlorideHCID 6344DichloromethaneHCID 14801Manganese dioxideHCID 159261931,4-Dimethyl-2-hydroxymethyl-(2'-nitrophenyl) pyrrole

Product 1

HCID 159261941,4-Dimethyl-3-(2'-nitrophenyl)pyrrole-carbaldehyde

Sources & evidence

ORD record
ord-03604a40786f415e8d8d6b4522908507
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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