Dichloromethane → 2-Butyl-5-chloro-3-(4-nitro-benzyl)-3h-imidazole-4-carbaldehyde

HRID 837961Notes

Reaction equation

HRID 837961 reaction equation
[Cl:23][CH2:24][Cl:25].[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][cH:6][c:7]([CH2:8][n:9]2[c:10]([CH2:17][CH2:18][CH2:19][CH3:20])[n:11][c:12]([Cl:16])[c:13]2[CH2:14][OH:15])[cH:21][cH:22]1.[O:26]=[Mn:27]=[O:28]>>[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][cH:6][c:7]([CH2:8][n:9]2[c:10]([CH2:17][CH2:18][CH2:19][CH3:20])[n:11][c:12]([Cl:16])[c:13]2[CH:14]=[O:15])[cH:21][cH:22]1

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 14801Manganese dioxideHCID 153564431-(4-Nitrobenzyl)-2-butyl-4-chloro-5-hydroxymethyl imidazole

Product 1

HCID 198153972-Butyl-5-chloro-3-(4-nitro-benzyl)-3h-imidazole-4-carbaldehyde

Sources & evidence

ORD record
ord-a65aabf902134c5bb996fa2d86fe6b0f
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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