Diallylamine → HCID 20324729, compound

HRID 838798Notes

Reaction equation

HRID 838798 reaction equation
[CH2:1]([NH:4][CH2:5][CH:6]=[CH2:7])[CH:2]=[CH2:3].[CH2:8]([S:12](Cl)(=[O:14])=[O:13])[CH:9]([CH3:11])[CH3:10]>C1C=CC=CC=1>[CH2:1]([N:4]([CH2:5][CH:6]=[CH2:7])[S:12]([CH2:8][CH:9]([CH3:11])[CH3:10])(=[O:14])=[O:13])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 31279DiallylamineHCID 1822361-Propanesulfonyl chloride, 2-methyl-

Product 1

HCID 20324729HCID 20324729, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A solution was formed containing 19.4 g. of diallylamine in 100 ml. of benzene. Then, 15.7 g. of isobutylsulfonyl chloride was added at such a rate that the temperature did not exceed 45° C. The mixture was stirred and refluxed for ten minutes, cooled, washed with 100 ml. of dilute hydrochloric acid and then with H2O. It was then dried over magnesium sulfate, filtered and evaporated to give 20.1 g. (02% of theory) of the product, a liquid, nD30 = 1.4697.

Workup

  1. customA solution was formed
  2. additioncontaining 19.4 g
  3. customdid not exceed 45° C
  4. temperaturerefluxed for ten minutes
  5. temperaturecooled
  6. washwashed with 100 ml
  7. dry with materialIt was then dried over magnesium sulfate
  8. filtrationfiltered
  9. customevaporated
  10. customto give 20.1 g

Sources & evidence

ORD record
ord-ceceb4f970b746f0b71e5a11ce916eae
Source dataset
uspto-grants-1978_06
Patent number
US04093445

Reaction notes

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