Neopentyl glycol → HCID 20324832, compound

HRID 838844Notes

Reaction equation

[C:1]([C:9]1[CH:10]=[C:11]([CH:20]=[C:21]([C:24]([CH2:27]C(C)(C)C)([CH3:26])[CH3:25])[C:22]=1[OH:23])[CH2:12][P:13]1(=[O:19])[O:18]CC[CH2:15][O:14]1)([CH2:4]C(C)(C)C)([CH3:3])[CH3:2].[CH3:32][C:33](C)([CH2:36]O)[CH2:34]O.C(C1C=C(C=C(C(CC(C)(C)C)(C)C)C=1O)CP(=O)(OC1C=CC=CC=1)OC1C=CC=CC=1)(CC(C)(C)C)(C)C.C(C1C=C(C=C(C(C)(C)C)C=1O)CP(=O)(OC1C=CC=CC=1)OC1C=CC=CC=1)(C)(C)C>>[C:1]([C:9]1[CH:10]=[C:11]([CH:20]=[C:21]([C:24]([CH3:27])([CH3:26])[CH3:25])[C:22]=1[OH:23])[CH2:12][P:13]1(=[O:19])[O:18][CH2:32][C:33]([CH3:36])([CH3:34])[CH2:15][O:14]1)([CH3:2])([CH3:3])[CH3:4]

Participants

Reactant 4

HCID 31344Neopentyl glycol

HCID 13651368HCID 13651368, compound

HCID 20324844HCID 20324844, compound

HCID 20324845HCID 20324845, compound

Product 1

HCID 20324832HCID 20324832, compound

Procedure

Similarly, 1-(3,5-di-tert-octyl-4-hydroxybenzyl)-1-oxo-2,6-dioxa-1-phosphacyclohexane is made by substituting 1,3-propanediol for 2,2-dimethyl-1,3-propanediol and diphenyl 3,5-di-tert-octyl-4-hydroxybenzylphosphonate for diphenyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate in the above example.

Sources & evidence

ORD record: ord-412782bfdc974040ab29618878d27889
Source dataset: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04093588

Reaction notes

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