HCID 54460329, compound → HCID 53946767, compound

HRID 839166Notes

Reaction equation

HRID 839166 reaction equation
[CH2:1]([O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][CH2:16][CH:17]=[CH:18][CH2:19][CH2:20]I)=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:22][C:23](=[O:28])[CH2:24][C:25](=[O:27])[CH3:26].[Li]>>[CH2:1]([O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][CH2:16][CH:17]=[CH:18][CH2:19][CH2:20][CH:24]([C:23](=[O:28])[CH3:22])[C:25](=[O:27])[CH3:26])=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 54460329HCID 54460329, compoundHCID 86735745HCID 86735745, compound

Product 1

HCID 53946767HCID 53946767, compound

Procedure

[I; Ar is 3-C6H5CH2OC6H4, R0 is H, R' and R" are CH3CO, Y is CH=CHCH2CH2 ] was prepared by reacting 6-(4-benzyloxyphenyl)-3-hexenyl iodide (Preparation D16) with lithium pentane-2,4-dione. The product was chromatographed on activated magnesium silicate and eluted with benzene.

Workup

  1. customwas prepared
  2. customThe product was chromatographed on activated magnesium silicate
  3. washeluted with benzene

Sources & evidence

ORD record
ord-3e6670f0f42e45a1acd816bb8abbbc27
Source dataset
uspto-grants-1978_06
Patent number
US04093736

Reaction notes

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