Boron tribromide → HCID 514324, compound

HRID 839173Notes

Reaction equation

C[O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]([C:20](=[O:23])[CH2:21][CH3:22])[C:16](=[O:19])[CH2:17][CH3:18].B(Br)(Br)Br>>[OH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]([C:16](=[O:19])[CH2:17][CH3:18])[C:20](=[O:23])[CH2:21][CH3:22]

Participants

Reactant 2

HCID 25134Boron tribromide

HCID 514319HCID 514319, compound

Product 1

HCID 514324HCID 514324, compound

Procedure

[I; Ar is 2-HOC6H4, R0 is H, R' and R" are CH3CH2CO, Y is CH2CH2CH2CH2 ] was prepared by demethylation of 4-[6-(2-methoxyphenyl)hexyl]-3,5-heptanedione (Example 46) with boron tribromide according to the procedure of Example 42f.

Sources & evidence

ORD record: ord-6e49989f16aa4c30b553893cb436cdad
Source dataset: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04093736

Reaction notes

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