HRID839210

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCn1cc(C=NO)c(-c2ccc([N+](=O)[O-])o2)n1

HCID54074725

N-{[1-Ethyl-3-(5-nitrofuran-2-yl)-1H-pyrazol-4-yl]methylidene}hydroxylamine

C10H10N4O4

结构：CC(C)n1cc(C=NO)c(-c2ccc([N+](=O)[O-])o2)n1

HCID54174528

未命名化合物

结构：O=[N+]([O-])c1ccc(-c2nn(-c3ccccc3)cc2C=NO)o1

HCID54343732

N-{[3-(5-Nitrofuran-2-yl)-1-phenyl-1H-pyrazol-4-yl]methylidene}hydroxylamine

C14H10N4O4

结构：Cn1cc(C=NO)c(-c2ccc([N+](=O)[O-])o2)n1

HCID54488696

N-{[1-Methyl-3-(5-nitrofuran-2-yl)-1H-pyrazol-4-yl]methylidene}hydroxylamine

C9H8N4O4

PRODUCTS

生成物

结构：CCn1cc(C=NOC(C)=O)c(-c2ccc([N+](=O)[O-])o2)n1

HCID53790506

未命名化合物

结构：CC(=O)ON=Cc1cn(C(C)C)nc1-c1ccc([N+](=O)[O-])o1

HCID53867451

未命名化合物

结构：CC(=O)ON=Cc1cn(-c2ccccc2)nc1-c1ccc([N+](=O)[O-])o1

HCID54390112

未命名化合物

PROCEDURE

实验过程

Following the same procedure and replacing 1-methyl-3-(5-nitro-2-furyl)pyrazole-4-carboxaldehydeoxime by an equivalent of 1-ethyl-3-(5-nitro-2-furyl)pyrazole-4-carboxaldehydeoxime, 1-isopropyl-3-(5-nitro-2-furyl)pyrazole-4-carboxaldehydeoxime and 3-(5-nitro-2-furyl)-1-phenylpyrazole-4-carboxaldehydeoxime, respectively, results in the corresponding preparation of: 1-ethyl-3-(5-nitro-2-furyl)pyrazole-4-carboxaldehyde-(O-acetyloxime), 1-isopropyl-3-(5-nitro-2-furyl)pyrazole-4-carboxaldehyde-(O-acetyloxime), and 3-(5-nitro-2-furyl)-1-phenylpyrazole-4-carboxaldehyde-(O-acetyloxime), respectively.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-41c22e8282814368b727acd82b56040e
来源数据集: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04093812
来源说明: uspto-grants-1978_06

反应 SMILES

CN1C=C(C=NO)[C:4]([C:10]2[O:11]C([N+]([O-])=O)=CC=2)=N1.[CH2:18]([N:20]1[CH:24]=[C:23]([CH:25]=[N:26][OH:27])[C:22]([C:28]2[O:29][C:30]([N+:33]([O-:35])=[O:34])=[CH:31][CH:32]=2)=[N:21]1)[CH3:19].[CH:36]([N:39]1[CH:43]=[C:42]([CH:44]=[N:45][OH:46])[C:41]([C:47]2[O:48][C:49]([N+:52]([O-:54])=[O:53])=[CH:50][CH:51]=2)=[N:40]1)([CH3:38])[CH3:37].[N+:55]([C:58]1[O:62][C:61]([C:63]2[C:67]([CH:68]=[N:69][OH:70])=[CH:66][N:65]([C:71]3[CH:76]=[CH:75][CH:74]=[CH:73][CH:72]=3)[N:64]=2)=[CH:60][CH:59]=1)([O-:57])=[O:56]>>[C:10]([O:27][N:26]=[CH:25][C:23]1[C:22]([C:28]2[O:29][C:30]([N+:33]([O-:35])=[O:34])=[CH:31][CH:32]=2)=[N:21][N:20]([CH2:18][CH3:19])[CH:24]=1)(=[O:11])[CH3:4].[C:61]([O:46][N:45]=[CH:44][C:42]1[C:41]([C:47]2[O:48][C:49]([N+:52]([O-:54])=[O:53])=[CH:50][CH:51]=2)=[N:40][N:39]([CH:36]([CH3:38])[CH3:37])[CH:43]=1)(=[O:62])[CH3:60].[C:10]([O:70][N:69]=[CH:68][C:67]1[C:63]([C:61]2[O:62][C:58]([N+:55]([O-:57])=[O:56])=[CH:59][CH:60]=2)=[N:64][N:65]([C:71]2[CH:72]=[CH:73][CH:74]=[CH:75][CH:76]=2)[CH:66]=1)(=[O:11])[CH3:4]