HCID 131711118, compound → HCID 12831068, compound

HRID 839255Notes

Reaction equation

HRID 839255 reaction equation
C[O:2]C1C=C(CNCCCNCCCCNCCCN)C=CC=1O.[Cl:25][C:26]1[CH:27]=[C:28](N2CC(=O)NC2=O)[CH:29]=[CH:30][CH:31]=1.COC1C=C(CNCCCNCCCCNCCCN)C=CC=1O.ClC1C=CC([N:70]2[CH2:76][C:74](=[O:75])[NH:73][C:71]2=[O:72])=CC=1>>[C:71]([NH:70][CH:76]([C:28]1[CH:29]=[CH:30][CH:31]=[C:26]([Cl:25])[CH:27]=1)[C:74]([OH:75])=[O:2])(=[O:72])[NH2:73]

Participants

3

Reactant 2

HCID 131711118HCID 131711118, compound2×HCID 131711119HCID 131711119, compound

Product 1

HCID 12831068HCID 12831068, compound

Procedure

Further, the same large scale reaction as in Example 10 was repeated except that DL-5-(3-chlorophenyl)hydantoin and Agrobacterium rhizogenes IFO 13259 were employed instead of DL-5-(4-chlorophenyl)hydantoin and Pseudomonas chlororaphis IFO 3904, respectively. From 1.0 g. of DL-5-(3-chlorophenyl)hydantoin 267 mg. of N-carbamoyl-2-(3-chlorophenyl)glycine was obtained.

Workup

  1. customFurther, the same large scale reaction as in Example 10

Sources & evidence

ORD record
ord-092e4251102d465690c51a4339c0fce4
Source dataset
uspto-grants-1978_06
Patent number
US04094741

Reaction notes

Loading…