HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 2-Diazonio-1-methoxy-3-oxo-5-[(trimethylsilyl)oxy]hepta-1,6-dien-1-olate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | p-Toluenesulfonyl azide | HCID 13661 | — |
| Reactant | Methyl 3-oxo-5-[(trimethylsilyl)oxy]hept-6-enoate | HCID 53718342 | — |
| Product | 2-Diazonio-1-methoxy-3-oxo-5-[(trimethylsilyl)oxy]hepta-1,6-dien-1-olate | HCID 53918353 | 83% |
Reaction Steps
In accordance with the process of Preparation 1, 3-oxo-5-trimethylsilyloxy-6-heptenoic acid methyl ester (360 mg; 1.47 mmol), p-toluenesulfonyl azide (290 mg; 1.47 mmol) and triethylamine (150 mg; 1.47 mmol) were used as starting materials to obtain 330 mg of 2-diazo-3-oxo-5-trimethylsilyloxy-6-heptenoic acid methyl ester as a yellow oily product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04094886 |
| Source dataset | uspto-grants-1978_06 |
| ORD ID | ord-57881d6eff9848cbbcd41388ed57880c |
| Source note | uspto-grants-1978_06 |