HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Acetylcyclopentene → 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Acetylcyclopentene | HCID 192925 | — |
| Reactant | 3,4-Dihydro-6,7-dimethoxyisoquinoline hydrochloride | HCID 2724664 | — |
| Reactant | 3,4-Dihydroisoquinoline--hydrogen chloride (1/1) | HCID 20463855 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one | HCID 12774492 | — |
Reaction Steps
When in Example 32 appropriate amounts of 3,4-dihydro-6,7-dimethoxyisoquinoline hydrochloride and 1-chylohexen-1-yl methyl ketone respectively are substituted for 3,4-dihydroisoquinoline hydrochloride and 1-cyclopenten-1-yl methyl ketone, 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one is obtained M.P. 129°-141° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04096147 |
| Source dataset | uspto-grants-1978_06 |
| ORD ID | ord-93740712527c4945a4bce8294a5728ce |
| Source note | uspto-grants-1978_06 |