反应详情

温度

60 °C

To a high-pressure reactor with a magnetic stirrer is charged 31.50 g (1.75 mol) water, 13.50 g (0.232 mol) acetone, 25.0 g (7.70×10−2 mol) octadecyl acrylate, 25.0 g (0.255 mol) α-methylene-γ-butyrolactone, 1.25 g (4.08×10−3 mol) sodium stearate, and 0.13 g (5.46×10−4 mol) sodium persulfate. Two freeze-pump-thaw cycles using liquid nitrogen sufficiently degass the reaction medium prior to sealing the reactor and heating to 60° C. The reaction is stirred for 16 hours at 60° C. before cooling to room temperature and drying under vacuum at elevated temperature for isolation.

1. customsufficiently degass the reaction medium
2. temperaturebefore cooling to room temperature
3. customdrying under vacuum at elevated temperature for isolation