Phenol → HCID 12329321, compound

Participants

Reaction Steps

0.31 grams (1.8 mmol.) of poly[Pd(CO)Cl], 0.39 g. (1.82 mmol.) of p-cumylphenol, 0.17 g. (1.8 mmol.) of phenol, 6 ml. of methylene chloride, 0.47 g. (3.64 mmol.) of diisopropylmonoethylamine were saturated with carbon monoxide during 3-hour reaction period. Subsequent work-up and analysis showed the presence of 0.19 grams (45% yield) of bis(p-cumylphenyl) carbonate and 0.14 (45% yield) of p-cumylphenyl(phenyl) carbonate and a trace (estimated 2% yield) of diphenyl carbonate.

Provenance & Evidence