HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrachlorophthalic anhydride → 2-(2-Isobutoxy-4-(dimethylamino)benzoyl)benzoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrachlorophthalic anhydride | HCID 8326 | — |
| Reactant | 1,3-Benzenediamine, N1,N1,N3,N3-tetramethyl- | HCID 89715 | — |
| Catalyst | Zincchloride | HCID 3007855 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | 2-(2-Isobutoxy-4-(dimethylamino)benzoyl)benzoic acid | HCID 23343377 | — |
Reaction Steps
In a manner similar to that of part A of Example 3 condensation of tetrachlorophthalic anhydride (1.92 g.) and N,N,N',N'-tetramethyl-m-phenylenediamine (1.64 g.) in contact with zinc chloride (1.35 g.) and with chlorobenzene (40-45 ml.) as diluent afforded 2-(2,4-bis(dimethylamino)benzoyl)-3,4,5,6-tetrachlorobenzoic acid (II: Y'2 = Y'4 = (CH3)2N, Z4 = Z'5 = Z'6 = Z7 = Cl) (m.p. 199°-201° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04096176 |
| Source dataset | uspto-grants-1978_06 |
| ORD ID | ord-00fc089ed7494f2fa6adce3dc56ffa53 |
| Source note | uspto-grants-1978_06 |