Ethyl diazoacetate → Ethyl 2-octylcycloprop-2-ene-1-carboxylate

HRID 840083Notes

Reaction equation

[CH:1]#[C:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[N+](=[CH:13][C:14]([O:16][CH2:17][CH3:18])=[O:15])=[N-]>>[CH2:3]([C:2]1[CH:13]([C:14]([O:16][CH2:17][CH3:18])=[O:15])[CH:1]=1)[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

Reactant 2

HCID 12192Ethyl diazoacetate

HCID 129971-Decyne

Product 1

HCID 22621698Ethyl 2-octylcycloprop-2-ene-1-carboxylate

Procedure

Ethyl 2-octylcycloprop-2-ene-1-carboxylate was prepared from 1-decyne and ethyl diazoacetate by the method of Mueller, P.; Pautex, N.; Helv. Chim Acta 1990, 73,1233.

Sources & evidence

ORD record: ord-3dfad42c45c74ee49ecc62633e34e13e
Source dataset: uspto-grants-2002_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06365549B2

Reaction notes

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