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HRID840459

反应详情

EQUATION

反应方程式

HRID 840459 的结构方程式

REACTANTS

反应物

2
结构：C#CC(O)c1ccc2c(c1)C(C)(C)CCC2(C)C
HCID11817362

未命名化合物

结构：COC(=O)c1cc(I)cn1C(=O)OC(C)(C)C
HCID54463778

未命名化合物

PRODUCTS

生成物

1
结构：COC(=O)c1cc(C#CC(O)c2ccc3c(c2)C(C)(C)CCC3(C)C)cn1C(=O)OC(C)(C)C
HCID54193334

未命名化合物

收率 99.5%

PROCEDURE

实验过程

Following the basic procedure of Example 11(d), by reacting 2 g (8.2 mmol) of α-ethynyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenemethanol with 3 g (8.5 mmol) of methyl N-tert-butoxycarbonyl-4-iodo-2-pyrrolecarboxylate, 3.8 g (98%) of the expected ester were obtained in the form of a brown oil.