HCID 67498719, compound → HCID 22620176, compound

Participants

Reaction Steps

A solution of N-Boc-2-(1-heptenyl)piperdine (3.92, 13.93 mmol) in 7 mL of ethanol was shaken under 58 psi of H2 pressure over 0.78 g Pd/C catalyst overnight, and then the mixture was filtered through Celite and concentrated to give 3.94 g (quantitative) of the product. No further purification was necessary. 1H NMR (250 MHz) δ4.20-4.15 (br s, 1 H), 3.99-3.85 (br d, 1 H), 2.79-2.70 (dt, 1 H), 1.59-1.25 (m, 21 H), 0.89-0.85 (t, 3 H); 13C NMR (62.7 MHz) 155.1 (s), 78.8 (s), 50.3 (s), 38.6 (s), 31.8 (s), 29.6 (s), 29.5 (s), 29.3 (s), 28.4 (s), 26.3 (s), 25.6 (s), 22.6 (s), 18.9 (s), 14.0 (s) ppm.

Provenance & Evidence