HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 841152Generated: October 25, 2026
Chlorotrimethylsilane → 1-Chloro-3,7-dimethyl-octa-2,6-diene
https://huagongshe.com/reaction/841152
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | Linalool | HCID 6549 | — |
| Catalyst | Bismuthyl (ion) | HCID 5237718 | — |
| Product | 1-Chloro-3,7-dimethyl-octa-2,6-diene | HCID 99106 | 83.2% |
Reaction Steps
To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were dropped in. Then the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06369248B1 |
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| Source dataset | uspto-grants-2002_04 |
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| ORD ID | ord-93b7fdeaec43433281661a380319a923 |
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| Source note | uspto-grants-2002_04 |
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