HCID 12017029, compound → HCID 11206192, compound

HRID 842441Notes

Reaction equation

HRID 842441 reaction equation
[OH:1][C@H:2]1[CH2:7][C@@H:6]([C:8]([O:10][CH2:11][CH3:12])=[O:9])[C@H:5]([CH3:13])[CH2:4][CH2:3]1.[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>C(Cl)Cl>[CH3:13][C@@H:5]1[CH2:4][CH2:3][C:2](=[O:1])[CH2:7][C@H:6]1[C:8]([O:10][CH2:11][CH3:12])=[O:9]

Participants

4

Reactant 2

HCID 12017029HCID 12017029, compoundHCID 178418287HCID 178418287, compound

Product 1

HCID 11206192HCID 11206192, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

reacting said ethyl (1R,2R,5R)-5-hydroxy-2-methylcyclohexane-1-carboxylate (10) with pyridinium chlorochromate in methylene chloride to produce ethyl(1R,2R)-2-methylcyclohexane-5-one-1-carboxylate (11),

Sources & evidence

ORD record
ord-99235f821ce3444db3b2643520d60bf5
Source dataset
uspto-grants-2002_04
Patent number
US06375943B1

Reaction notes

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