HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 11489564, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 1-(Benzyloxy)-4-(bromomethyl)benzene | HCID 10492756 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 11489564 | HCID 11489564 | 92.2% |
Reaction Steps
To bromide 1 (9.7 g, 35.0 mmol) in toluene (300 mL) was added triphenylphosphine (10.1 g, 38.5 mmol). The reaction was stirred at reflux overnight. The reaction mixture was cooled to room temperature and the precipitate was filtered, washed twice with diethyl ether, and dried in vacuo to afford 17.4 g (92%) of 2 as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06376524B1 |
| Source dataset | uspto-grants-2002_04 |
| ORD ID | ord-cf703fd111194da6b4dcb51254f46670 |
| Source note | uspto-grants-2002_04 |