HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → Bis[1-(3-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]Sebacate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Heptane | HCID 8900 | — |
| Reactant | 3-Bromo-1-propanol | HCID 12308 | — |
| Reactant | Bis(1-hydroxy-2,2,6,6-tetramethyl-4-piperidinyl)decandioate | HCID 11272241 | — |
| Reactant | Ethylacetate heptane | HCID 21899848 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | Bis[1-(3-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]Sebacate | HCID 22507641 | — |
Reaction Steps
Tributyltin hydride is added dropwise to a solution of 3-bromo-1-propanol and excess bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) sebacate in chlorobenzene. The mixture is heated to facilitate reaction. The crude reaction mixture is passed through silica gel with heptane and then heptane/ethyl acetate to afford the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06376584B1 |
| Source dataset | uspto-grants-2002_04 |
| ORD ID | ord-78b796e842784b2ea1053da309573660 |
| Source note | uspto-grants-2002_04 |