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HRID845257

反应详情

EQUATION

反应方程式

HRID 845257 的结构方程式

REACTANTS

反应物

2
结构：COC(=O)C(=Cc1cccc([N+](=O)[O-])c1)C(C)=O
HCID1536427

Methyl 2-[(3-nitrophenyl)methylene]-3-oxobutanoate

C12H11NO5

结构：C/C(N)=C/C(=O)OCCN1C(=O)c2ccccc2C1=O
HCID67903522

未命名化合物

PRODUCTS

生成物

1
结构：COC(=O)C1=C(C)NC(C)=C(C(=O)OCCN2C(=O)c3ccccc3C2=O)C1c1cccc([N+](=O)[O-])c1
HCID13799831

未命名化合物

收率 83.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Prepared by a method analogous to that of Example 1(a) from 14.95 g (60 mmol) of 2-(3-nitrobenzylidene)-acetoacetic acid methyl ester and 16.46 g (60 mmol) of 3-amino-crotonic acid-(2-phthalimidoethyl)ester in ethanol. 25.25 g (83%) of yellow crystals melting at 181°-182° C. are obtained.