HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cesium carbonate → Methyl-6-[(6-methoxy-6-oxohexyl)thio]-7-eicosynoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cesium carbonate | HCID 10796 | — |
| Reactant | Hexanoic acid, 6-mercapto-, methyl ester | HCID 11788469 | — |
| Reactant | Methyl 6-bromo-7-eicosynoate | HCID 15003192 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Methyl-6-[(6-methoxy-6-oxohexyl)thio]-7-eicosynoate | HCID 15003194 | — |
Reaction Steps
A mixture of methyl 6-bromo-7-eicosynoate, methyl 6-mercaptohexanoate (1.21 g) in 70 ml DMF was treated with Cs2CO3 (2.44 g) as in Example 45 to give 1.02 g of methyl-6-[(6-methoxy-6-oxohexyl)thio]-7-eicosynoate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04758594 |
| Source dataset | uspto-grants-1988_07 |
| ORD ID | ord-0a27e20308bd4d75ae3e937848e68b63 |
| Source note | uspto-grants-1988_07 |