HuagongsheHuagongshe Chemistry Print Report · For research reference only
5,5-Diethoxy-3-methyl-2-pentenal → 6-Bromo-3-methyl-1,1-diethoxy-3,5-hexadiene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5,5-Diethoxy-3-methyl-2-pentenal | HCID 53767196 | — |
| Reactant | 1-Bromo-6,6-dimethoxy-4-methylhexa-1,3-diene | HCID 54005359 | — |
| Product | 6-Bromo-3-methyl-1,1-diethoxy-3,5-hexadiene | HCID 54085110 | — |
Reaction Steps
6-Bromo-3-methyl-1,1-diethoxy-3,5-hexadiene is prepared under the conditions described earlier for the preparation of 6-bromo-3-methyl-1,1-dimethoxy-3,5-hexadiene. Starting with 5,5-diethoxy-3-methyl-2-pentenal (4.67 g; 25.1 mmol), 6-bromo-3-methyl-1,1-diethoxy-3,5-hexadiene (5.1 g) is obtained in 77.5% yield. The structure of the product obtained is confirmed by the infrared spectrum and the proton nuclear magnetic resonance spectrum.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04760193 |
| Source dataset | uspto-grants-1988_07 |
| ORD ID | ord-6c1bb876cff3455394b249663d453de1 |
| Source note | uspto-grants-1988_07 |