Potassium Hydroxide → HCID 178443540, compound

HRID 846021Notes

Reaction equation

HRID 846021 reaction equation
C([O:3][C:4](=[O:20])[CH:5]([C:13]([C-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1)=[O:14])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])C.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26].[OH-].[K+]>C(O)C>[C-:15]1([C:13]([CH:5]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[C:4]([OH:20])=[O:3])=[O:14])[CH:16]=[CH:17][CH:18]=[CH:19]1.[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[Fe+2:26]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 178443539HCID 178443539, compound

Product 1

HCID 178443540HCID 178443540, compoundYield 103.4%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

An amount of 20.5 g of ferrocenoylnonanic acid ethyl ester prepared in the above (1) and 5.1 g of potassium hydroxide were refluxed in ethanol for 2 hours and then treated with acid to obtain 19.7 g of ferrocenoylnonanic acid of the following formula [7]. ##STR27##

Workup

  1. additiontreated with acid

Sources & evidence

ORD record
ord-33881e9b12d04ad4827598f80c3e6d6d
Source dataset
uspto-grants-1992_08
Patent number
US05135637

Reaction notes

Loading…