Bromine → HCID 19771321, compound

HRID 846036Notes

Reaction equation

HRID 846036 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-:18])=[O:17])[C:11]=2[CH3:19])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Br:20]Br>C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-:18])=[O:17])[C:11]=2[CH2:19][Br:20])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 24408BromineHCID 19771316HCID 19771316, compound

Product 1

HCID 19771321HCID 19771321, compoundYield 77.4%

Reagents, catalysts & solvents 1

HCID 7187Benzoyl PeroxideCatalyst

Procedure

The procedure of Example 8 was used except that the starting material was 0.80 g of 2-(3-nitrophenyl)-6-nitrotoluene which was reacted with 0.49 g of bromine and 33 mg of benzoyl peroxide. In this way, 0.80 g (77% yield) of yellowish crystals were obtained.

Sources & evidence

ORD record
ord-90070bda48f04cac9c0bec83ecf3d610
Source dataset
uspto-grants-1992_08
Patent number
US05135838

Reaction notes

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